Beilstein J. Org. Chem.2019,15, 2534–2543, doi:10.3762/bjoc.15.246
potentials recorded for the Ag+/Ag couple, which are strongly solvent dependent and vary from 0.04 V in acetonitrile to 0.65 V in DCM [98]. Therefore, oxidation should occur in the latter solvent, while silver(I) complexation could be expected in more coordinating solvents. Consequently, addition of a
PDF
Graphical Abstract
Figure 1:
Well-defined catalysts for alkyne metathesis.
Beilstein J. Org. Chem.2010,6, 1022–1024, doi:10.3762/bjoc.6.115
scaffold with C3v symmetry bearing three axial pyridyl appendages is presented. This pre-organized hexadentate ligand allows complexation of silver(I). The crystal structure of the complex was established.
Keywords: cyclitol; glyco-scaffolds; hexadentate; scyllo-inositol; silver(I) complexation